Earlier this year, researchers at Los Alamos National Lab discovered a new passive detection technique for heavy elements that works better the more the shielding... their idea involves cosmic muons. Read about it in a BBC science article or the original article in Nature cited below.
These highly energetic particles (GeV range) shower the earth at the rate of 10,000 per sq. meter per minute and mostly pass right through anything they encounter. However, they will scatter just slightly and the scattering angle is highly dependent on the atomic mass. Although it is not specific to nuclear materials, this technique can therefore differentiate between ordinary materials in say a container or truck and heavier materials like Uranium/Plutonium and shielding such as lead . So a property of this approach is that greater or denser the shielding, the greater the angle of scattering. This forms a passive substitute for (active) X-ray scanning that can even be used on live cargo, such as sheep, to detect a concealed cargo.
The original article appearing in Nature (below), which have to have online access to or purchase, shows the shape of shielded matter can reconstructed exhibiting the detection capability and providing formulas on how the scattering works.
Nature 422, 277 (20 March 2003); doi:10.1038/422277a, "Surveillance: Radiographic imaging with cosmic-ray muons"
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